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  MK-13 Safety Data Sheet for Chemicals

  Part 1 Chemicals and Firm Identification

  Chemical Name (Product Name) :MK-13 (ADHESIVE BLACK INK)
  Product Code ：MK－K31，MK－K32，MK－K32H
  Vendor name ：KEYENCE CORPORATION
  Zip code ：533－8555
  address : 1-3-14 Higashi-Nakajima, Higashiyodogawa-ku, Osaka-shi, Osaka Prefecture, Japan
  Responsible department   : Printing Division
  telephone number ：＋81－6－6379－1111
  fax ：＋81－6－6379－2222
  24-hour emergency hotline in China : 0532-8388-9090 (National Chemical Accident Emergency Hotline)
  Recommended and Restricted Uses   : Dedicated to industrial inkjet printers
  Email ：sds＿mk＠keyence．co．jp
  Date of preparation   : October 1, 2009
  Date of revision   : 01/04/2023
化学品名称（产品名称） ：MK－13（黑油墨（强粘性 ））（ADHESIVE BLACK INK） 产品代码 ：MK－K31，MK－K32，MK－K32H 供应商名称 ：KEYENCE CORPORATION 邮政编码 ：533－8555 地址 ：日本国大阪府大阪市东淀川区东中岛 1－3－14 负责部门 ：打印事业部 电话号码 ：＋81－6－6379－1111 传真 ：＋81－6－6379－2222 中国国内 24 小时应急咨询电话 ：0532－8388－9090（国家化学事故应急咨询专线） 推荐用途和限制用途 ：专用于工业喷码机 电子邮箱 ：sds＿mk＠keyence．co．jp 编制日期 ：2009年10月01日 修订日期 ：2023年04月01日| 化学品名称（产品名称） | ：MK－13（黑油墨（强粘性 ））（ADHESIVE BLACK INK） | | :--- | :--- | | 产品代码 | ：MK－K31，MK－K32，MK－K32H | | 供应商名称 | ：KEYENCE CORPORATION | | 邮政编码 | ：533－8555 | | 地址 | ：日本国大阪府大阪市东淀川区东中岛 1－3－14 | | 负责部门 | ：打印事业部 | | 电话号码 | ：＋81－6－6379－1111 | | 传真 | ：＋81－6－6379－2222 | | 中国国内 24 小时应急咨询电话 | ：0532－8388－9090（国家化学事故应急咨询专线） | | 推荐用途和限制用途 | ：专用于工业喷码机 | | 电子邮箱 | ：sds＿mk＠keyence．co．jp | | 编制日期 | ：2009年10月01日 | | 修订日期 | ：2023年04月01日 |

  Part 2 Overview of Hazards

  GHS Hazard Category

  Physical Hazards:
   - Flammable liquids : Category 2
   Health Hazards:
   - Acute toxicity
  Oral   : Not categorized
  Percutaneous   : Not categorized
  Inhalation: (Gas)   :not applicable
  (Steam)   : Category 4
  (Dust)   : Cannot be classified
  (Smoke)   : Cannot be classified
  arouse   : Category 2
  Eye irritation   : Category 2A
  : Cannot be classified
  : Cannot be classified
  sex   : Cannot be classified
  : Cannot be classified
  : Cannot be classified
  Effects of milk   : Cannot be classified
  Systemic toxicity One exposure   : Category 2 (kidney)
  Category 3 (respiratory irritation, anesthetic effects)
  Systemic toxicity with repeated exposure   : Category 1 (Nervous System)
经口 ：不分类 经皮 ：不分类 吸入：（气体） ：不适用 （蒸气） ：类别 4 （粉尘） ：不能分类 （烟雾） ：不能分类 激 ：类别 2 眼刺激性 ：类别 2A ：不能分类 ：不能分类 性 ：不能分类 ：不能分类 ：不能分类 乳的影响 ：不能分类 系统毒性 一次接触 ：类别 2（肾脏） 类别 3（呼吸道刺激，麻醉效应） 系统毒性 反复接触 ：类别 1（神经系统）| 经口 | ：不分类 | | :--- | :--- | | 经皮 | ：不分类 | | 吸入：（气体） | ：不适用 | | （蒸气） | ：类别 4 | | （粉尘） | ：不能分类 | | （烟雾） | ：不能分类 | | 激 | ：类别 2 | | 眼刺激性 | ：类别 2A | | | ：不能分类 | | | ：不能分类 | | 性 | ：不能分类 | | | ：不能分类 | | | ：不能分类 | | 乳的影响 | ：不能分类 | | 系统毒性 一次接触 | ：类别 2（肾脏） | | | 类别 3（呼吸道刺激，麻醉效应） | | 系统毒性 反复接触 | ：类别 1（神经系统） |
  Environmental Hazards:
  •   Acute aquatic toxicity
  •   Chronic aquatic toxicity

  GHS Label Elements

  Pictograms:

  Signal words

  -dangerous

  Hazard Statement

  •   Highly flammable liquids and vapors
  •   Causes skin irritation
  •   Causes severe eye irritation
  •   Harmful to inhalation (vapors)
  •   May cause damage to the kidneys
  •   May cause respiratory irritation
  •   May cause drowsiness or vertigo
  •   Long-term or repeated exposure can cause damage to the nervous system

  Precautionary Statement

  【Precautionary Measures】

  •   Keep away from heat sources, sparks, open flames, and hot surfaces. 1. No smoking.
  •   Keep containers tightly closed.
  •   Prevent fire caused by static electricity and sparks.
  •   Use explosion-proof appliances, ventilation, lighting, etc.
  • Wear appropriate protective gloves, goggles, masks, face shields, and gowns.
  •   Wash your hands thoroughly after the procedure and rinse your mouth.
  •   Only operate outdoors or in a well-ventilated place.
  •   Do not inhale gases, vapors, sprays.
  •   No eating, drinking, or smoking is allowed in the workplace.
  •   Please read the product manual carefully before use.
  【Incident Response】
  •   If inhaled: If you feel unwell, call a poison control center or seek medical attention.
  • In case of contact with eyes: Rinse carefully with water for a few minutes. If you wear contact lenses and can easily remove them, remove them. Continue rinsing.
       If eye irritation persists: Seek medical attention.
  • In case of skin (or hair) contact: Immediately remove all contaminated clothing. Rinse skin with water and shower.
  • Remove contaminated clothing and wash it before reuse. If exposed or concerned, seek medical attention.
       - In case of fire: use a dry powder/foam/carbon dioxide fire extinguisher.

  【Safe Storage】

-Store in an airtight container, avoid direct sunlight, and store in a well-ventilated, dark place. Keep out of reach of small children.

  【Disposal】

- Contents and containers shall be disposed of in accordance with the relevant laws and regulations of the local government. It is forbidden to discharge into the environment.

  Part 3 Composition/composition information

  mixture

  Chemical name or generic name   Concentration or concentration range   Registry number (CAS number)
2-Methyl Ethyl Ketone 2－butanone）
2－丁酮 （Methyl Ethyl Ketone；2－butanone）| 2－丁酮 | | :--- | | （Methyl Ethyl Ketone；2－butanone） |
 80 − 90 % 80 − 90 % 80-90%80-90 \% 78 − 93 − 3 78 − 93 − 3 78-93-378-93-3
Chromium-containing dyeing (3 (3(3(3 valence.) ) ))) （Chrome complex dye（III））
含铬金属染 (3 价 ) （Chrome complex dye（III））| 含铬金属染 $(3$ 价 $)$ | | :--- | | （Chrome complex dye（III）） |
10 − 20 % 10 − 20 % 10-20%10-20 \% (The Cr content in the product is less than 1.0 % ) 1.0 % ) 1.0%)1.0 \%)
10-20% （产品中的Cr 含量小于 1.0%)| $10-20 \%$ | | :---: | | （产品中的Cr 含量小于 | | $1.0 \%)$ |
   trade secret
化学名或通用名 浓度或浓度范围 登记号（CAS 号） "2－丁酮 （Methyl Ethyl Ketone；2－butanone）" 80-90% 78-93-3 "含铬金属染 (3 价 ) （Chrome complex dye（III））" "10-20% （产品中的Cr 含量小于 1.0%)" 商业秘密| 化学名或通用名 | 浓度或浓度范围 | 登记号（CAS 号） | | :--- | :---: | :---: | | 2－丁酮 <br> （Methyl Ethyl Ketone；2－butanone） | $80-90 \%$ | $78-93-3$ | | 含铬金属染 $(3$ 价 $)$ <br> （Chrome complex dye（III）） | $10-20 \%$ <br> （产品中的Cr 含量小于 <br> $1.0 \%)$ | 商业秘密 |

  Part 4 First Aid Measures

  First aid methods for different types of contact

  inhale

- If you feel unwell when inhaling vapors or gases, you should move the patient to a place with fresh air, rest, and maintain a position conducive to breathing. If you feel unwell, call a Poison Control Center or seek medical attention.
- When inhaling large amounts of vapors, gases, etc., immediately move the patient to fresh air to keep them warm and quiet.
- Artificial respiration should be performed when breathing is irregular or respiratory arrest. Avoid swallowing vomit. Seek immediate medical attention.

  Skin-to-skin contact

  •   Wipe off the adhesion with a cloth as soon as possible.
  •   Remove contaminated clothing.
  • Rinse thoroughly with plenty of water and soapy water or skin detergent. Do not use solvents or thinners.
  • Seek medical attention if you experience changes in the surface of your skin or cause irritation, pain, and discomfort.

  Eye contact

- Immediately rinse with plenty of clean, running water for more than 15 minutes. If you wear contact lenses and can easily remove them, remove them. Rinse all areas of the eyelid thoroughly.
   - Call a poison control center or seek medical attention immediately.

  Ingestion

  •   In case of accidental ingestion, you should be quiet and seek medical attention immediately.
  •   Do not allow them to swallow vomit.
  •   According to your doctor's instructions, do not induce vomiting otherwise.

  Acute and late effects, main symptoms, and major health effects

  Part 5 Fire protection measures

  extinguishant

- Carbon dioxide fire extinguishers, foam fire extinguishers, dry powder fire extinguishers, dry sand

  Particularly dangerous

  Special extinguishing methods

- Wear appropriate protective gear because combustion produces flammable gases, toxic gases, etc., and may cause hypoxia.
  • In order to prevent the spread of fire, it is necessary to ensure that it is safe to remove combustibles from the surrounding area.
  • Depending on the scale of the fire, if there is a danger associated with firefighting activities, evacuate quickly.
  •   Use the specified extinguishing agent.

  Special protective equipment for the protection of firefighters

  Part 6 Emergency Handling of Spills

  Protective measures, protective equipment and emergency response procedures for operators

  • Appropriate protective equipment (gloves, protective masks, aprons, goggles, etc.) should be worn during operation.
  •   Quickly remove nearby ignition sources, hot objects, and surrounding flammable materials.
  •   Have a proper fire extinguisher ready in case of a fire.

  Environmental protection measures

-Take care not to leak products and cause environmental impact by discharging them into rivers, etc.

  Methods of containment and removal of spilled chemicals and disposal materials used

  • Recycle the spill into a container that can be sealed and move to a safe place.
  •   Adhesions, wastes, etc., shall be disposed of in accordance with relevant laws and regulations.
  • Recycling is done with tools that use materials that do not spark due to impact or static electricity.
  •   It is adsorbed with dry sand, soil and other non-combustible substances and then recycled.
  •   When the leakage is large, an embankment is built with a mound of earth to stop the overflow.

  Precautions to prevent the occurrence of secondary hazards

- Do not enter the leakage area and avoid unrelated personnel to prevent secondary hazards.

  Part 7 Handling, Disposal and Storage

  Operational disposition

  Technical measures

  • Make sure that there are no work or high-temperature objects such as open flames or electric sparks in the vicinity.
  • To avoid injury from inhalation and contact, appropriate protective gear should be worn.
  • Measures should be taken in accordance with relevant laws and regulations to prevent contamination caused by the infiltration and spread of spills into water sources and soil.
    - Wear anti-static work clothes and shoes during work, and use tools that do not produce sparks.
       Partial or full ventilation
       - To prevent poisoning and hypoxia, appropriate ventilation equipment should be used.

  Precautions

  • Restrictions on the use of the package by the operator are measured, and it is stipulated that no one other than the user is allowed to touch the package after opening.
  •   Open the vessel valve if necessary, otherwise it should be kept closed for a long time.
  Precautions for safe disposal
   - Do not mix with other solutions.

  stockpile

  Conditions for safe storage
  •   Avoid rain and direct sunlight, and store in a well-ventilated and cold place.
  •   Keep away from smoke and heat.
  •   After opening, it should be stored tightly closed.
  •   Do not place substances that produce oxygen after decomposition around the area.
  •   Storage is carried out in accordance with the provisions and conditions of relevant laws and regulations.
  •   To prevent theft, it should be locked.
  Safe packaging materials
   - Use the container provided by our company for storage.

Part 8 Exposure Control and Personal Protection

  Allowable concentration

  • China: 2-BUTANONE: PC-TWA 300 mg / m 3 300 mg / m 3 300mg//m^(3)quad300 \mathrm{mg} / \mathrm{m}^{3} \quad PC-STEL 600 mg / m 3 600 mg / m 3 600mg//m^(3)600 \mathrm{mg} / \mathrm{m}^{3}
  •   ACGIH: 2-butanone: 200ppm

  Engineering Control Methods

  • In order to prevent the retention of volatile vapors, it is necessary to set up explosion-proof devices such as comprehensive ventilation and local exhaust.
  •   Set up an exhaust device to avoid vapor retention.
  •   Grounding treatment for liquid transportation, absorption, stirring and other devices.
  •   Use explosion-proof operating equipment.
  •   Equipment that does not produce high temperature and ignition sources should be used near the operation site.

  Security management

  • The environment should be tested with detectors and tubes, and protective gear should be worn as needed.
  •   When carrying out electrostatic painting work, conductive boots should be worn.

  Personal protective equipment

  • Respiratory protection: Wear a gas mask for organic gases and an air mask according to the working environment.
  •   Hand protection: Wear protective gloves
  •   Eye protection: Wear safety glasses and goggles
  • Skin and body protection: Wear safety and health protective clothing to avoid direct contact with the skin

  Part 9 Physicochemical properties

  Shape, shape and color   : Black liquid
  smell   : Solvent odor
  Odor threshold   : No data
  Ph   : No data
  Melting point/freezing point   : No data
  Boiling point, initial boiling point, and boiling range   : 80 ∘ C 80 ∘ C 80^(@)C80^{\circ} \mathrm{C} (based on 2-butanone)
  flash point ： − 4.1 ∘ C − 4.1 ∘ C -4.1^(@)C-4.1^{\circ} \mathrm{C}
  Autoignition temperature   : 505 ∘ C 505 ∘ C 505^(@)C505{ }^{\circ} \mathrm{C} (based on 2-butanone)
  Flame flammability (solid, gas)   : No data
  Explosion limit : Upper limit: 11.5vol\%; Lower limit: 1.8vol\% (based on 2-butanone)
  Vapor pressure : 10500 Pa (based 20 ∘ C 20 ∘ C 20^(@)C20^{\circ} \mathrm{C} on 2-butanone)
  Vapor density   : 2.41 (based on 2-butanone)
  Evaporation rate   : No data
  Specific gravity (relative density) : 0.85 ± 0.05 g / cm 3 : 0.85 ± 0.05 g / cm 3 :0.85+-0.05g//cm^(3): 0.85 \pm 0.05 \mathrm{~g} / \mathrm{cm}^{3}
  Solubility (water)   : Insoluble
  n-octanol/water partition coefficient   : 0.29 (based on 2-butanone)
  Decomposition temperature   : No data
  viscosity ： 3.14 ± 0.3 mPa ⋅ s 3.14 ± 0.3 mPa ⋅ s 3.14+-0.3mPa*s3.14 \pm 0.3 \mathrm{mPa} \cdot \mathrm{s}
物态、形状和颜色 ：黑色液体 气味 ：溶剂气味 气味阈值 ：无数据 pH 值 ：无数据 熔点／凝固点 ：无数据 沸点、初沸点和沸程 ： 80^(@)C（按2－丁酮计） 闪点 ：-4.1^(@)C 自燃温度 ： 505^(@)C（以2－丁酮计） 火焰易燃性（固体、气体） ：无数据 爆炸极限 ：上限：11．5vol\％；下限：1．8vol\％ （按 2－丁酮计） 蒸气压 ： 10500 Pa （ 20^(@)C 按2－丁酮计） 蒸气密度 ：2．41（按2－丁酮计） 蒸发速率 ：无数据 比重（相对密度） :0.85+-0.05g//cm^(3) 溶解性（水） ：不溶 n－辛醇／水分配系数 ：0．29（按2－丁酮计） 分解温度 ：无数据 粘度 ： 3.14+-0.3mPa*s| 物态、形状和颜色 | ：黑色液体 | | :--- | :--- | | 气味 | ：溶剂气味 | | 气味阈值 | ：无数据 | | pH 值 | ：无数据 | | 熔点／凝固点 | ：无数据 | | 沸点、初沸点和沸程 | ： $80^{\circ} \mathrm{C}$（按2－丁酮计） | | 闪点 | ：$-4.1^{\circ} \mathrm{C}$ | | 自燃温度 | ： $505{ }^{\circ} \mathrm{C}$（以2－丁酮计） | | 火焰易燃性（固体、气体） | ：无数据 | | 爆炸极限 | ：上限：11．5vol\％；下限：1．8vol\％ （按 2－丁酮计） | | 蒸气压 | ： 10500 Pa （ $20^{\circ} \mathrm{C}$ 按2－丁酮计） | | 蒸气密度 | ：2．41（按2－丁酮计） | | 蒸发速率 | ：无数据 | | 比重（相对密度） | $: 0.85 \pm 0.05 \mathrm{~g} / \mathrm{cm}^{3}$ | | 溶解性（水） | ：不溶 | | n－辛醇／水分配系数 | ：0．29（按2－丁酮计） | | 分解温度 | ：无数据 | | 粘度 | ： $3.14 \pm 0.3 \mathrm{mPa} \cdot \mathrm{s}$ |

  Part 10 Stability and reactivity

  stability : It is considered that the storage and disposal are stable in accordance with the provisions of relevant laws and regulations.
  Dangerous reactions   : No dangerous reactions occur in the standard state.
  Conditions to avoid : There is a risk of explosion due to impact, friction, pyrotechnics or other ignition sources.
  Incompatible substances : Avoid mixing with oxidants, alkaline substances, reducing agents, oxidizing solids, oxidizing liquids and gases under pressure.
  Dangerous decomposition products: Harmful gases such as carbon monoxide, carbon dioxide, and nitrogen oxides are produced due to combustion.
稳定性 ：认为遵循相关法律法规的规定进行保管及处置时是稳定的。 危险反应 ：在标准状态下不会发生危险反应。 应避免的条件 ：会有因受撞击、摩擦、烟火或其他引火源而导致爆炸的风险。 不相容的物质 ：避免与氧化剂、碱性物质、还原剂、氧化性固体，氧化性液体及压力下气体混触。 危险的分解产物： 因燃烧会产生一氧化碳、二氧化碳、氮氧化物等有害气体。| 稳定性 | ：认为遵循相关法律法规的规定进行保管及处置时是稳定的。 | | :--- | :--- | | 危险反应 | ：在标准状态下不会发生危险反应。 | | 应避免的条件 | ：会有因受撞击、摩擦、烟火或其他引火源而导致爆炸的风险。 | | 不相容的物质 | ：避免与氧化剂、碱性物质、还原剂、氧化性固体，氧化性液体及压力下气体混触。 | | 危险的分解产物： | 因燃烧会产生一氧化碳、二氧化碳、氮氧化物等有害气体。 |

  Part 11 Toxicological information

  Acute toxicity

  2-butanone:
  Oral : : :: Rat LD 50 = 5520 mg / kg 50 = 5520 mg / kg 50=5520mg//kg50=5520 \mathrm{mg} / \mathrm{kg} , Category 5
  Percutaneous : : :: Rabbit LD 50 > 5000 mg / kg 50 > 5000 mg / kg 50 > 5000mg//kg50>5000 \mathrm{mg} / \mathrm{kg} , not classified
  inhale : : :: Rat LC 50 = 11700 ppm / 4 H 50 = 11700 ppm / 4 H 50=11700ppm//4H50=11700 \mathrm{ppm} / 4 \mathrm{H}
  inhale   (Smoke)
   : : :: No data
经口 : 大鼠 LD 50=5520mg//kg, 类别 5 经皮 : 家兔 LD 50 > 5000mg//kg, 不分类 吸入 : 大鼠 LC 50=11700ppm//4H 吸入 （烟雾） : 无数据| 经口 | $:$ 大鼠 LD $50=5520 \mathrm{mg} / \mathrm{kg}$, 类别 5 | | :--- | :--- | | 经皮 | $:$ 家兔 LD $50>5000 \mathrm{mg} / \mathrm{kg}$, 不分类 | | 吸入 | $:$ 大鼠 LC $50=11700 \mathrm{ppm} / 4 \mathrm{H}$ | | 吸入 | （烟雾） | | | $:$ 无数据 |

  Chromium-containing dyes (3 valent):

  Oral: rat LD50>2.0g/kg
   Percutaneous: No data
   Inhalation : No data
   Inhalation (smoke): No data

  Corrosive or irritated skin

  2-MEKONE
: It has been documented that "it does not show irritation even when it comes into contact with human skin" and "it shows mild or moderate irritation in the skin test of rabbits".
   Chromium-containing dyes (3-valent): non-irritating.

  Eye erosion or irritation

2-Butanone : Hypothetical eye irritation has been documented in cases of human vapor exposure; In the eye irritation test in rabbits, the mean scores after 24 hours were 2.5 for corneal opacity and 2 for conjunctival redness, respectively, but almost recovered within 7 days.
   Chromium-containing dyes (3-valent): non-irritating

  Respiratory or skin allergies

Respiratory allergies: 2 − 丁 2 − 丁 2-丁2-丁丁 ketones / / /// chromium-containing metal dyes (3-valent): no data for skin allergies:
2-MEK: It has been documented that one case of contact dermatitis has been documented based on the same original literature, but no other symptoms have been reported, and it is negative in the mouse ear swelling test.
   Chromium-containing metal dye (3-valent): No skin irritation.

  Germ cell mutage

  2-Budanone : Negative mammalian red blood cell micronucleus test.
   Chromium-containing dyes (3-valent): Data not available.

  carcinogenicity

2-MEK: Classified as 1 (inadequate) in the EPA.
   Chromium-containing dyes (3-valent): Data not available.

  Reproductive toxicity

2-MEK: It has been documented that the inhalation exposure teratogenicity test in rats confirmed that it can cause fetal malformations, but the second test did not show any malformation symptoms of delayed ossification and mutation. In addition, the teratogenicity test of inhalation exposure in mice did not confirm the deformity symptoms of low body weight and mutation of animal pups, and the above can be known to have minimal effects.
   Chromium-containing dyes (3-valent): Data not available.

  Specific target organ system toxicity with one exposure

  2-MEKONE
The effect on rat kidneys has been documented in the dose range of category 2. In addition to the kidneys, this substance has respiratory irritating and anesthetic effects.
有记载显示，在类别 2 的剂量范围内可以确认对 大鼠肾脏的影响。除了肾脏，此物质还具有呼吸 道刺激和麻醉效应。| 有记载显示，在类别 2 的剂量范围内可以确认对 | | :--- | | 大鼠肾脏的影响。除了肾脏，此物质还具有呼吸 | | 道刺激和麻醉效应。 |
  Make the chromium full-layer cyanogen material (3 prices): the secondary material is missing
2－丁酮 "有记载显示，在类别 2 的剂量范围内可以确认对 大鼠肾脏的影响。除了肾脏，此物质还具有呼吸 道刺激和麻醉效应。" 令铬全层氿料（3 价）：次料斩缺 | 2－丁酮 | 有记载显示，在类别 2 的剂量范围内可以确认对 <br> 大鼠肾脏的影响。除了肾脏，此物质还具有呼吸 <br> 道刺激和麻醉效应。 | | :--- | :--- | | 令铬全层氿料（3 价）：次料斩缺 | |

  Specific target organ system toxicity with repeated exposure

2-MEK: It has been documented that the hands and wrists are paralyzed in the case of occupational exposure, and it is implied that the central nervous system will be damaged in the case of occupational exposure, and three cases have been found to affect the central nervous system, so it is believed that the target organs are the central nervous system and peripheral nervous system.
   Chromium-containing dyes (3-valent): Data not available

  Dangerous to inhale

  2-Butanone : May be harmful if swallowed or inhaled into the trachea.
   Chromium-containing dyes (3-valent): Data not available

  Part 12 Ecological Information

  Ecotoxicity
-2-BUTANONE: Crimson LC50>100mg/L/96H

  Persistence and degradability

  -No information (no data by product)

  Potential bioaccumulation

  -No information (no data by product)

  Migration in soils

  - No information

  Part 13 Disposal

  Residual waste

  •   Contents and containers should be disposed of as industrial waste.
  • Wastewater discharge, treatment and incineration shall be disposed of in accordance with the provisions and conditions of relevant laws and regulations.
    - Sludge and incineration residues generated by wastewater discharge and treatment should also be disposed of as industrial waste.
    - Industrial waste shall be disposed of in accordance with the provisions of relevant laws and regulations, or entrusted to a licensed industrial waste processor for disposal.

  Contaminated containers and packaging

- Flammable vapors formed by volatilization of residual liquids in empty containers are at risk of fire and explosion, so the residual liquids and vapors should be removed before disposal.
- Industrial waste shall be disposed of in accordance with the provisions of relevant laws and regulations, or entrusted to a licensed industrial waste processor for disposal.

  SECTION 14 SHIPPING INFORMATION

  •   United Nations Dangerous Goods Number (UN Number): 1210
  • UN Shipping Name: Printing inks, flammable, or printing ink related materials (including printing ink thinners or reducing agents), flammable
  •   United Nations Risk Classification: 3
  •   Packing group: II
  •   Marine Pollutants (Yes/No): No

  Special precautions for transport

- Care should be taken to avoid falling and damage to the container during handling and disposal. Avoid rain and direct sunlight, and load in a well-ventilated place.
-When loading, it should be kept away from smoke and heat sources. Carriage shall be carried out in accordance with the provisions and conditions of relevant laws and regulations.
-Since it is a flammable liquid, do not mix it with substances that produce oxygen after decomposition.

  Part 15 Regulatory Information

  Regulatory Information

The following laws, regulations and standards provide for the safe use, storage, transportation, loading and unloading, classification and marking of chemicals:
Regulations on the Safety Management of Hazardous Chemicals (2011 State Council Decree)
   List of Hazardous Chemicals (2015)
   Hazardous Chemicals Classification Information Sheet (2015)
   List of Dangerous Goods GB 12268-2012
   Regulations on the Administration of the Transport of Dangerous Goods on Road (2013)
"Classification and Name Coding of Dangerous Goods" GB6944-2012
"Contents and Sequence of Items in Safety Data Sheets for Chemicals" GB/T 16483-2008
General Principles for Classification and Hazard Disclosure of Chemicals GB 13690-2009
GB 20581－2006； GB 20592－2006； GB 20593－2006； GB 20594－2006； GB
20598－2006 ； GB 20599－2006； GB 20601－2006
"Code for the Use of Personal Occupational Disease Protective Equipment in Organic Solvent Workplaces" GBZ/T195-2007
Occupational exposure limits for hazardous factors in the workplace – Part 1 Chemical hazards GBZ 2.1-2007
Regulations on the Preparation of Chemical Safety Labels GB15258-2009
Code for Classification and Labelling of Chemicals – Part 7: Flammable Liquids GB 30000.7-2013
Code of Classification and Labelling of Chemicals Part 18: Acute Toxicity GB 30000.18-2013
Specification for classification and labelling of chemicals – Part 19: Skin corrosion/irritation GB 30000.19-2013
Guidelines for Classification and Labelling of Chemicals Part 20: Severe Eye Injury/Eye Irritation
GB 30000．20－2013
Guidelines for Classification and Labelling of Chemicals Part 25: Specific Target Organ Toxicity – Secondary Exposures
GB 30000．25－2013
Guidelines for Classification and Labelling of Chemicals Part 26: Specific Target Organ Toxicity - Recurrent Exposure
GB 30000．26－2013

  Section 16 Other Information

  References

  •   ACGIH (2007)
  • http://joh.med.uoeh-u.ac.jp/oel/index.html of the Industrial Hygiene Society of Japan (2007~2008).
    －ICSC CARD http：／／www．nihs．go．jp／ICSC
    -GHS Classification Results Database, the Technical Infrastructure for Product Evaluation, http://www.safe.nite.go.jp/ghs/ghs_index.html (Japan)
    －JIS Z 7253：2019
    -Ohmsha, Ltd.: Solvent Fact Sheet, GHS Classification Results Information (Japan)
    -Product Safety Data Sheet (MSDS) provided by the manufacturer of raw materials (Japan)

  disclaimer

This SDS is based on the latest information (hazard information, operation information, etc.) related to the product and its ingredients obtained at the time of production or revision, but it does not cover all information, and the contents may be updated or revised due to new information. In addition, the data recorded in this SDS is a representative value of this product and is not a guaranteed value.
If you wish to mix this product with materials other than those specified by the Company, or if you want to use it under special conditions other than those specified by the Company, please ensure that it is safe to use the product.
   The symbol "-" in the above information indicates that there is no relevant information at present.