Chemical Safety Data Sheet
Part 1: Chemical and Company Identification
Chemical Name in Chinese: Dibutyl phthalate Common or Trade Name of Chemical:
Chemical English Name: dibutyl diphthalate Company Name: Zibo Lanfan Chemical Co., Ltd. Address: Yixi North Road, Qilu Chemical Industrial Park, Shandong Postal Code: 255411 Email:
Fax number: (Country or region code) (Area code) (Phone number) 0533-7526062
Company emergency phone: (Country or region code) (Area code) (Phone number) Technical specification code: Effective date: Year Month Day National emergency telephone:
Part 2: Composition/Information on Ingredients
This chemical is: Pure substance Chemical name: Dibutyl phthalate CAS No. Name Mass Percentage Concentration (%) Hazard Classification Symbol RR Hazard Phrases 84-74-2 Dibutyl phthalate > 50∼⩽100>50 \sim \leqslant 100
Xn 62-63
Health hazards:
For humans: The threshold concentration detectable by the most sensitive individuals is 0.00026mg//L0.00026 \mathrm{mg} / \mathrm{L} . The threshold concentration for the photic reflex effect on the eyes is 0.00016mg//L0.00016 \mathrm{mg} / \mathrm{L} , while the threshold for brain bioelectrical activity is 0.00011∼0.00012mg//L0.00011 \sim 0.00012 \mathrm{mg} / \mathrm{L} . Workers producing plasticizers may develop polyneuritis, spinal neuritis, and cerebral polyneuritis.
Effects on skin and eyes:
This substance can be absorbed in small amounts through intact skin. A single contact with skin or eye mucosa does not cause irritation, but repeated exposure may lead to severe irritation. According to some experimental data, it may cause mild sensitization.
For animals:
Mice exposed to an aerosol concentration of LD_(50)=25mg//L\mathrm{LD}_{50}=25 \mathrm{mg} / \mathrm{L} for 2 hours showed irritation of the eye mucosa and upper respiratory tract mucosa during intoxication.
Severe irritation, difficulty breathing, ataxia, hind limb paralysis; some animals exhibited superficial anesthesia and clonic convulsions.
Environmental Hazard: This substance is harmful to the environment, with particular attention required for water pollution.
Fire and Explosion Hazard: Flammable, posing a fire risk when exposed to open flames, high temperatures, or strong oxidizers.
Part 4 First Aid Measures
Skin contact: Remove contaminated clothing and rinse thoroughly with soap and water Eye contact: Rinse with clean water for at least 10 minutes and seek medical attention
Inhalation: Move the patient to fresh air and administer oxygen or artificial respiration if necessary Ingestion: Rinse mouth, drink plenty of water, and seek medical attention
Part 5 Firefighting Measures
Hazardous properties: Flammable, poses a fire hazard when exposed to open flames, high temperatures, or strong oxidizers Hazardous combustion products: Carbon monoxide, carbon dioxide, dense smoke
Fire extinguishing methods and agents: Use foam, carbon dioxide, dry powder, or sand to extinguish. Water is ineffective for firefighting
Firefighting Precautions: Firefighting water must not enter sewers or rivers. The product decomposes during combustion, producing harmful dense smoke. Inhaling the smoke may cause health hazards. It is recommended to wear a respirator during firefighting operations and to cool surrounding sealed containers with water.
Part 6: Accidental Release Measures
Emergency Procedures: Eliminate ignition sources and stop the leak. Quickly evacuate personnel from the contaminated area to a safe zone and isolate the area, strictly restricting access. Emergency responders should wear self-contained positive pressure respirators and anti-static clothing. Stop the leak if possible without risk. Prevent entry into sewers, drainage systems, or other confined spaces. For small spills: Absorb residual liquid with sand, activated carbon, or other inert materials. Collect the leaked liquid in sealed containers as much as possible and dispose of it in accordance with waste disposal regulations.
Elimination Methods: Strictly follow the handling and storage requirements specified in Parts 7 and 8 of this document.
Part 7 Handling and Storage
Precautions for operation: Operate in a cool, well-ventilated area. Keep containers dry and tightly closed.
Storage precautions: Keep the container tightly closed. Do not empty the container by applying pressure. Opened containers must be resealed and stored upright to prevent leakage. Smoking is strictly prohibited. Store separately from oxidizers, strong alkalis, and strong acids. Avoid direct sunlight. Unauthorized personnel are not permitted to enter. Containers must not be used to store other substances. Pay attention to product labels. Maintain good ventilation in the storage area, keep away from heat sources, open flames, and avoid direct sunlight. Store...
Part 8 Exposure Controls/Personal Protection
Maximum Allowable Concentration: 2.5mg//m32.5 \mathrm{mg} / \mathrm{m} 3 Permissible Exposure Concentration - Time Weighted Average (PEC-TWA): 1.0mg//m31.0 \mathrm{mg} / \mathrm{m} 3 Monitoring Method: Gas Chromatography Engineering Controls: Enclose the production process and enhance ventilation Eye protection: Wear chemical safety goggles Body protection: Wear general work clothing Hand protection: Wear oil-resistant rubber gloves
Other precautions: Smoking, eating, and drinking are prohibited at the work site. Avoid consuming alcoholic beverages before work. Undergo pre-employment and regular medical examinations.
Part 9 Physical and Chemical Properties
Appearance and Properties: Colorless liquid with a distinctive odor pH Value: Neutral Freezing Point ( ^(@)C{ }^{\circ} \mathrm{C} ): -35 Relative density (water = 1): 1.048(25^(@)C)1.048\left(25^{\circ} \mathrm{C}\right) Boiling point (^(@)C):340\left({ }^{\circ} \mathrm{C}\right): 340 Relative vapor density (air = 1): None Saturated vapor pressure (kPa): 0.1 kPa//142.9^(@)C\mathrm{kPa} / 142.9^{\circ} \mathrm{C} Heat of combustion (kcal/mol): 2058
Critical temperature ( ^(@)C{ }^{\circ} \mathrm{C} ): 502
Critical pressure (MPa): 1.72 Logarithm of octanol/water partition coefficient: Not available Flash point (^(@)C):⩾160\left({ }^{\circ} \mathrm{C}\right): \geqslant 160
Solubility: Insoluble in water, miscible with common organic solvents such as alcohols, ethers, benzene, and acetone
Main uses: Used in industries such as plastics, rubber, paints, lubricants, and emulsifiers Other physicochemical properties: Viscosity: 16.3mPa*S(25^(@)C)16.3 \mathrm{mPa} \cdot \mathrm{S}\left(25^{\circ} \mathrm{C}\right)
Part 10: Stability and Reactivity
Stability: Very stable at room temperature; prolonged boiling may cause partial decomposition, releasing monoesters. Incompatible Materials: Strong acids, strong bases, oxidizing agents. Conditions to Avoid: Open flames, high heat. Polymerization Hazard: Will not occur Decomposition products: Carbon monoxide, carbon dioxide, dense smoke
Part 11 Toxicological Information
Acute toxicity: Oral LD50 in rats LD_(50)\mathrm{LD}_{50} , workplace maximum allowable concentration 5mg//m^(3)5 \mathrm{mg} / \mathrm{m}^{3}
Chronic toxicity: Impairs human fertility, affects healthy development of fetuses in the womb Irritation: No data available Sensitization: No data available Mutagenicity: No data available Teratogenicity: No data available Carcinogenicity: No data available Other: No data available
Part 12 Ecological Information
Ecotoxicity: No data available Biodegradability: No data available Non-biodegradability: No data available Bioaccumulation or biological accumulation: No data available Other adverse effects: This product must not be discharged into waterways or soil
Part 13 Waste Disposal
Waste Characteristics: Hazardous Waste Disposal method: Treat by controlled incineration
Disposal Notes: Empty containers can be discarded as waste or recycled, but incompletely emptied containers should be treated as special waste
Part 14 Transport Information
Dangerous Goods Number: No data available UN Number: 3082 Packaging Mark: Environmentally Hazardous Substance Packing group: III Packing method: The product should be packed in iron drums
Transport precautions: Handle with care during transportation to avoid severe impact and rain
Part 15 Regulatory information
Regulations on the Safety Management of Chemical Hazardous Materials
"Classification and Labeling of Commonly Used Hazardous Chemicals" (GB 13690-92)
"Classification and Numbering of Dangerous Goods" (GB 6944-86) "List of Dangerous Goods" (GB 12268-90)
Part 16 Other Information
References: "Solvent Handbook", "Handbook of Physical and Chemical Properties of Chemical Products" Date of Completion: Department Completing the Form: Data Review Unit: Revision Notes: Additional Information:
1. This product shall not be used for purposes other than those specified in the technical documentation without prior consultation with the supplier and obtaining their written operational disposal notice. Since the specific conditions of product use are beyond the supplier's control, the user is responsible for ensuring compliance with relevant laws and regulations during use.
2. The information provided in this Safety Data Sheet is solely for meeting safety requirements and is compiled based on our current knowledge. This material does not serve as a guarantee of the product's performance or characteristics. It is the user's responsibility to take all necessary measures to comply with existing laws and regulations.