1.Identification 鉴定
1.1 GHS Product identifier GHS 产品标识符
| Product name 产品名称 | Carboxymethyl cellulose 羧甲基纤维素 |
|---|
1.2 Other means of identification
其他识别方式
| Product number 产品编号 | - |
|---|---|
| Other names 其他名称 | sodium,2,3,4,5,6-pentahydroxyhexanal,acetate 2,3,4,5,6-五羟基己醛乙酸钠 |
1.3 Recommended use of the chemical and restrictions on use
该化学品的推荐用途和使用限制
| Identified uses 已确定的用途 | For industry use only. 仅供行业使用。 |
|---|---|
| Uses advised against 建议不要使用 | no data available 无可用数据 |
1.4 Supplier's details 供应商详细信息
| Company | WWW.GuideChem.COM |
|---|---|
| Address | 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China 中国浙江省杭州市古墩路701号紫金广场3号楼C座8楼 310030 |
| Telephone | +86-571-89739798 |
| Fax | 86(21)54365166 |
1.5 Emergency phone number 紧急电话号码
| Emergency phone number 紧急电话号码 | +86-571-89739798 |
|---|---|
| Service hours 服务时间 | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). 周一至周五，上午 9 点至下午 5 点（标准时区：UTC/GMT +8 小时）。 |
2.Hazard identification 危险识别
2.1 Classification of the substance or mixture
物质或混合物的分类
Not classified. 未分类。
2.2 GHS label elements, including precautionary statements
GHS 标签元素，包括预防声明
| Pictogram(s) 象形图 | No symbol. 没有符号。 |
|---|---|
| Signal word 信号词 | No signal word. 没有信号词。 |
| Hazard statement(s) 危险说明 | none |
| Precautionary statement(s) 预防措施声明 | |
| Prevention | none |
| Response | none |
| Storage | none |
| Disposal | none |
2.3 Other hazards which do not result in classification
其他不导致分类的危害
none 没有
3.Composition/information on ingredients
成分/成分信息
3.1 Substances 物质
| Chemical name 化学名称 | Common names and synonyms 常用名和同义词 | CAS number CAS号 | EC number EC编号 | Concentration |
|---|---|---|---|---|
| Carboxymethyl cellulose 羧甲基纤维素 | Carboxymethyl cellulose 羧甲基纤维素 | 9004-32-4 | none | 100% |
4.First-aid measures 急救措施
4.1 Description of necessary first-aid measures
必要急救措施说明
General advice 一般建议
Consult a physician. Show this safety data sheet to the doctor in attendance.
请咨询医生。向主治医生出示此安全数据表。
If inhaled 如果吸入
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
如果吸入，请将人移入新鲜空气中。如果没有呼吸，则进行人工呼吸。请咨询医生。
In case of skin contact
在皮肤接触的情况下
Wash off with soap and plenty of water. Consult a physician.
用肥皂和大量水洗净。请咨询医生。
In case of eye contact
在眼神接触的情况下
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
用大量清水彻底冲洗至少 15 分钟，并咨询医生。
If swallowed 如果吞咽
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
永远不要用嘴给失去知觉的人任何东西。用水漱口。请咨询医生。
4.2 Most important symptoms/effects, acute and delayed
最重要的症状/影响，急性和迟发性
no data available 无可用数据
4.3 Indication of immediate medical attention and special treatment needed, if necessary
如有必要，需要立即就医和特殊治疗
no data available 无可用数据
5.Fire-fighting measures 消防措施
5.1 Extinguishing media 灭火介质
Suitable extinguishing media
合适的灭火介质
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
使用喷水剂、抗酒精泡沫、干粉或二氧化碳。
5.2 Specific hazards arising from the chemical
化学品引起的特定危害
no data available 无可用数据
5.3 Special protective actions for fire-fighters
消防员的特殊保护措施
Wear self-contained breathing apparatus for firefighting if necessary.
如有必要，佩戴自给式呼吸器进行灭火。
6.Accidental release measures
意外释放措施
6.1 Personal precautions, protective equipment and emergency procedures
个人预防措施、防护设备和应急程序
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
使用个人防护装备。避免灰尘形成。避免吸入蒸气、雾气或气体。确保充分通风。将人员疏散到安全区域。避免吸入灰尘。有关个人保护，请参阅第 8 节。
6.2 Environmental precautions
环境预防措施
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
如果安全的话，防止进一步泄漏或溢出。不要让产品进入下水道。必须避免排放到环境中。
6.3 Methods and materials for containment and cleaning up
收容和清理的方法和材料
Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.
取货并安排处置。清扫并铲起。保存在合适的密闭容器中进行处置。
7.Handling and storage 处理和储存
7.1 Precautions for safe handling
安全处理的注意事项
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
避免接触皮肤和眼睛。避免形成灰尘和气溶胶。避免接触 - 使用前获得特殊说明。在形成灰尘的地方提供适当的排气通风。有关注意事项，请参阅第 2.2 节。
7.2 Conditions for safe storage, including any incompatibilities
安全储存的条件，包括任何不相容性
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
存放在阴凉处。将容器密封在干燥通风的地方。
8.Exposure controls/personal protection
暴露控制/个人防护
8.1 Control parameters 控制参数
Occupational Exposure limit values
职业暴露限值
no data available 无可用数据
Biological limit values 生物极限值
no data available 无可用数据
8.2 Appropriate engineering controls
适当的工程控制
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
按照良好的工业卫生和安全规范进行处理。在休息前和工作日结束时洗手。
8.3 Individual protection measures, such as personal protective equipment (PPE)
个人防护措施，如个人防护装备 （PPE）
Eye/face protection 眼睛/面部保护
Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
带侧护罩的安全眼镜符合 EN166 标准。使用根据适当的政府标准（如 NIOSH（美国）或 EN 166（欧盟））进行测试和批准的护眼设备。
Skin protection 皮肤保护
Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
穿不透水的衣服。防护设备的类型必须根据特定工作场所危险物质的浓度和数量来选择。用手套处理。手套在使用前必须进行检查。使用适当的手套脱下技术（不接触手套的外表面）以避免皮肤接触本产品。使用后，根据适用法律和良好的实验室规范处理受污染的手套。洗手并擦干双手。所选防护手套必须符合欧盟指令 89/686/EEC 及其衍生标准 EN 374 的规范。
Respiratory protection 呼吸防护
Wear dust mask when handling large quantities.
处理大量物品时请戴上防尘口罩。
Thermal hazards 热危害
no data available 无可用数据
9.Physical and chemical properties
物化性质
| Physical state 物理状态 | no data available 无可用数据 |
|---|---|
| Colour | no data available 无可用数据 |
| Odour | no data available 无可用数据 |
| Melting point/ freezing point 熔点/凝固点 | -27\u00b0C(lit.) -27\u00b0C（lit.） |
| Boiling point or initial boiling point and boiling range 沸点或初始沸点和沸程 | 186\u00b0C(lit.) 186\u00b0C（lit.） |
| Flammability | no data available 无可用数据 |
| Lower and upper explosion limit / flammability limit 爆炸下限和上限/可燃性限值 | no data available 无可用数据 |
| Flash point 闪点 | 108\u00b0C(lit.) 108\u00b0C（lit.） |
| Auto-ignition temperature 自燃温度 | 370\u00b0C |
| Decomposition temperature 分解温度 | no data available 无可用数据 |
| pH | no data available 无可用数据 |
| Kinematic viscosity 运动粘度 | no data available 无可用数据 |
| Solubility | no data available 无可用数据 |
| Partition coefficient n-octanol/water (log value) 正辛醇/水分配系数（对数值） | no data available 无可用数据 |
| Vapour pressure 蒸汽压 | no data available 无可用数据 |
| Density and/or relative density 密度和/或相对密度 | no data available 无可用数据 |
| Relative vapour density 相对蒸气密度 | no data available 无可用数据 |
| Particle characteristics 颗粒特性 | no data available 无可用数据 |
10.Stability and reactivity 稳定性和反应性
10.1 Reactivity 反应
no data available 无可用数据
10.2 Chemical stability 化学稳定性
Stable under recommended storage conditions.
在推荐的储存条件下稳定。
10.3 Possibility of hazardous reactions
危险反应的可能性
no data available 无可用数据
10.4 Conditions to avoid 要避免的条件
no data available 无可用数据
10.5 Incompatible materials 不相容的材料
no data available 无可用数据
10.6 Hazardous decomposition products
有害分解产物
no data available 无可用数据
11.Toxicological information
毒理学信息
Acute toxicity 急性毒性
- Oral: no data available
口服：无可用数据 - Inhalation: no data available
吸入：无数据 - Dermal: no data available
皮肤：无可用数据
Skin corrosion/irritation
皮肤腐蚀/刺激
no data available 无可用数据
Serious eye damage/irritation
严重的眼睛损伤/刺激
no data available 无可用数据
Respiratory or skin sensitization
呼吸道或皮肤致敏
no data available 无可用数据
Germ cell mutagenicity 生殖细胞致突变性
no data available 无可用数据
Carcinogenicity 致癌性
no data available 无可用数据
Reproductive toxicity 生殖毒性
no data available 无可用数据
STOT-single exposure STOT-单次曝光
no data available 无可用数据
STOT-repeated exposure STOT-重复曝光
no data available 无可用数据
Aspiration hazard 误吸危险
no data available 无可用数据
12.Ecological information 生态信息
12.1 Toxicity 毒性
- Toxicity to fish: no data available
对鱼类的毒性：无数据 - Toxicity to daphnia and other aquatic invertebrates: no data available
对水蚤和其他水生无脊椎动物的毒性：无数据 - Toxicity to algae: no data available
对藻类的毒性：无可用数据 - Toxicity to microorganisms: no data available
对微生物的毒性：无数据
12.2 Persistence and degradability
持久性和可降解性
no data available 无可用数据
12.3 Bioaccumulative potential
生物蓄积潜力
no data available 无可用数据
12.4 Mobility in soil 在土壤中的流动性
no data available 无可用数据
12.5 Other adverse effects 其他不良反应
no data available 无可用数据
13.Disposal considerations 处置注意事项
13.1 Disposal methods 处置方法
Product 产品
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
这些材料可以通过转移到有执照的化学销毁厂或通过烟气洗涤进行控制焚烧来处置。不要通过储存或处置污染水、食品、饲料或种子。不要排放到下水道系统。
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
14.Transport information
14.1 UN Number
| ADR/RID: Not dangerous goods. | IMDG: Not dangerous goods. | IATA: Not dangerous goods. |
14.2 UN Proper Shipping Name
| ADR/RID: unknown |
| IMDG: unknown |
| IATA: unknown |
14.3 Transport hazard class(es)
| ADR/RID: Not dangerous goods. | IMDG: Not dangerous goods. | IATA: Not dangerous goods. |
14.4 Packing group, if applicable
| ADR/RID: Not dangerous goods. | IMDG: Not dangerous goods. | IATA: Not dangerous goods. |
14.5 Environmental hazards
| ADR/RID: no | IMDG: no | IATA: no |
14.6 Special precautions for user
no data available
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available
15.Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Carboxymethyl cellulose | Carboxymethyl cellulose | 9004-32-4 | none |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Not Listed. | ||
| EC Inventory | Not Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Not Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
| Vietnam National Chemical Inventory | Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
16.Other information
Information on revision
| Creation Date | Aug 12, 2017 |
|---|---|
| Revision Date | Aug 12, 2017 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
