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忢品安全数据表 MSDS  Product Safety Data Sheet MSDS

第一部分: 产品和公司标识 Part One: Product and Company Identity

本 PSDS/MSDS 文件中引用的电池产品为消费产品。根据 OSHA 的规定，电池被认为是"物品"，不符合 OSHA 危害沟通标准 PSDS/SDS 的要求，适用于"工作场所的危险化学品"。此外，电池在全球协调制度下被视为"物品"，不受 GHS 标签和 SDS 分类标准的限制。本 PSDS 文件是为回应有关电池使用、安全及符合法例的要求而提供的。
The battery products referenced in this PSDS/MSDS document are consumer products. Under OSHA regulations, batteries are considered "articles" and do not meet the requirements of OSHA's Hazard Communication Standard PSDS/SDS for "Hazardous Chemicals in the Workplace." In addition, batteries are considered "articles" under the Globally Harmonized System and are not subject to GHS labeling and SDS classification standards. This PSDS document is provided in response to requirements regarding battery use, safety and compliance with legislation.
产品名称：碱性电池（NANFU，EXCELL，NANFENG，RB 或其他 OEM 自有品牌）
Product name: Alkaline battery (NANFU, EXCELL, NANFENG, RB or other OEM own brands)
产品标识：碱性二氧化锰电池 Product identification: alkaline manganese dioxide battery
名 称：LR03（AAA）；LR6（AA）；LR14（C）; LR20（D）;LR8D425（AAAA）;6LR61（9V）
Name: LR03 (AAA); LR6 (AA); LR14 (C); LR20 (D); LR8D425 (AAAA); 6LR61 (9V)
标称电压: 1.5 V / ( 6 L R 61 : 9.0 V 1.5 V / ( 6 L R 61 : 9.0 V 1.5V//(6LR 61:9.0V1.5 \mathrm{~V} /(6 L R 61: 9.0 \mathrm{~V} ) Nominal voltage: 1.5 V / ( 6 L R 61 : 9.0 V 1.5 V / ( 6 L R 61 : 9.0 V 1.5V//(6LR 61:9.0V1.5 \mathrm{~V} /(6 L R 61: 9.0 \mathrm{~V} )
产品用途：能源 Product use: energy
日 期：2024-01-01 Date: 2024-01-01
公司信息 Company information
生产企业名称： Production company name:
地址：福建省南平市工业路 102号，编 353000
Address: No. 102 Gongye Road, Nanping City, Fujian Province, No. 353000
传真：+865994008873599 Fax: +865994008873599
电话: +86 5998731146 Phone: +86 5998731146
电子邮件: Service@nanfu.com Email: Service@nanfu.com
紧急电话： 24 小时紧急响应热线：400-8873599(中国)
Emergency hotline: 24-hour emergency response hotline: 400-8873599 (China)

第二部分: 危害识别 Part 2: Hazard Identification

(a) 分类 (a) Classification
根据2012年的 OSHA 危害传播标准（29 CFR 1910.1200），该化学品不被认为是危险的。该产品是一个密封的电池，因此不需要根据 OSHA 危害传播标准的 MSDS，除非破裂。所指出的危险是针对电池破裂的。
This chemical is not considered hazardous under the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). This product is a sealed battery and therefore does not require an MSDS according to OSHA Hazard Communication Standards unless ruptured. The hazard noted is for battery rupture.
皮肤腐蚀/过敏 Skin corrosion/allergy 第二类 Category 2
严重眼睛损伤/眼睛刺激 Serious eye damage/eye irritation 第一类 Category 1
特定靶器官毒性(反复暴露) Specific target organ toxicity (repeated exposure) 第一类 Category 1
皮肤腐蚀/过敏 第二类 严重眼睛损伤/眼睛刺激 第一类 特定靶器官毒性(反复暴露) 第一类| 皮肤腐蚀/过敏 | 第二类 | | :---: | :---: | | 严重眼睛损伤/眼睛刺激 | 第一类 | | 特定靶器官毒性(反复暴露) | 第一类 |

(b) GHS 标签内容，包括预防说明 (b) GHS label content, including precautionary statements

紧急情况概述 Emergency Overview

危险信号词 red flag words
风险声明 Risk statement
引起皮肤过敏 Cause skin allergies
造成严重的眼睛损伤 causing serious eye damage
这种产品是一种含有化学物质的物品。安全信息是提供给销售后产品暴露用的。产品的预期使用不应导致暴露出化学物质。这是一个电池。破裂时：存在上述危险。
This product is an item that contains chemicals. Safety information is provided for post-market product exposure. Intended use of the product should not result in exposure to chemicals. This is a battery. In the event of rupture: the above hazard exists.
外观：银 物理状态：固体 Appearance: Silver Physical State: Solid

浐聂安全数婮表 MSDS Safety Data Sheet MSDS

该产品是一种含有化学物质的物品。安全信息是提供给接触的物品作为销售。产品的预期使用不应导致化学物质的暴露。这是一个电池，破裂时：存在上述危险。
This product is an item containing chemicals. Safety information is provided to contacts as items are sold. Intended use of the product should not result in exposure to chemicals. This is a battery and in the event of rupture: the hazards described above exist.
警示：如果被充电、燃烧、与不同类型的电池混合、向后插入或拆卸，可能发生爆炸或泄漏，并造成烧伤。请同时更换所有用过的电池。不要把电池放在口袋或钱包里。请勿拆卸电池标签。
WARNING: May explode or leak and cause burns if charged, burned, mixed with different types of batteries, inserted backwards, or removed. Please replace all used batteries at the same time. Do not carry batteries in your pocket or purse. Do not remove the battery label.

潜在健康影响： Potential health effects:

这种产品中的化学物质和金属都装在一个密封的罐子里。除非电池泄漏内部物质的暴露不会发生，暴露在高温下或是机械，物理，或电滥用。损坏的电池会释放出高浓度的氢氧化钾，具有腐蚀性。预计氢氧化钾的潜在泄漏量为 2 到 20 毫升，具体取决于电池的大小。
The chemicals and metals in this product come in a sealed jar. Exposure of internal contents will not occur unless the battery leaks, is exposed to high temperatures or is subjected to mechanical, physical, or electrical abuse. A damaged battery will release high concentrations of potassium hydroxide, which is corrosive. The estimated potential leakage volume of potassium hydroxide is 2 to 20 ml, depending on the size of the battery.
眼睛接触：与电池内容物接触可能导致严重的刺激和烧伤。眼睛可能会受伤。
Eye Contact: Contact with battery contents may cause severe irritation and burns. Eye injuries may occur.
皮肤接触：接触电池内容物可能导致严重的刺激和烧伤。
Skin Contact: Contact with battery contents may cause severe irritation and burns.
吸 入：吸入因热或电池大量泄漏而释放的蒸气或烟雾可能会引起呼吸和眼睛刺激。
Inhalation: Inhalation of vapors or fumes released by heat or a large battery leak may cause respiratory and eye irritation.
吞 食：由于电池大小，预计不会吞咽。如果吞食较小的 AAA/AAAA 电池，可能会发生室息。吞食电池内容物（从泄漏的电池中)可能导致口腔、喉咙和肠道烧伤和损伤。
Swallowing: Due to the size of the battery, swallowing is not expected. If smaller AAA/AAAA batteries are swallowed, asphyxia may occur. Swallowing battery contents (from a leaking battery) can cause burns and injuries to the mouth, throat and intestines.

第三部分:成分组成/成分信息 Part 3: Ingredient composition/ingredient information

化学名称 chemical name CAS No. 含量（%） content(%) 等级 grade
二氧化锰 Manganese dioxide 1313 − 13 − 9 1313 − 13 − 9 1313-13-91313-13-9 36 − 44 36 − 44 36-4436-44 Xn , R 20 / 22 Xn , R 20 / 22 Xn,R20//22\mathrm{Xn}, \mathrm{R} 20 / 22
锌 7440 − 66 − 6 7440 − 66 − 6 7440-66-67440-66-6 13 − 18 13 − 18 13-1813-18 N , R 50 / 53 N , R 50 / 53 N,R50//53\mathrm{~N}, \mathrm{R} 50 / 53
KOH ( 40 % ) KOH ( 40 % ) KOH(40%)\mathrm{KOH}(40 \%) 1310 − 58 − 3 1310 − 58 − 3 1310-58-31310-58-3 4 − 9 4 − 9 4-94-9
石墨, 天然的/人造的 Graphite, natural/artificial 7782 − 42 − 5 7782 − 42 − 5 7782-42-57782-42-5 1 − 4 1 − 4 1-41-4 Xn , R 22 , R 35 Xn , R 22 , R 35 Xn,R22,R35\mathrm{Xn}, \mathrm{R} 22, \mathrm{R} 35
钢 7439 − 89 − 6 7439 − 89 − 6 7439-89-67439-89-6 10 − 18 10 − 18 10-1810-18
铜 12597 − 71 − 6 12597 − 71 − 6 12597-71-612597-71-6 2 − 4 2 − 4 2-42-4
氧化锌 zinc oxide 1314 − 13 − 2 1314 − 13 − 2 1314-13-21314-13-2 < 1 < 1 < 1<1
Ni -镀层 Ni-plating 7440 − 02 − 0 7440 − 02 − 0 7440-02-07440-02-0 < 0.5 < 0.5 < 0.5<0.5
水, 纸, 塑料, 其它 water, paper, plastic, other -- 全下其它 Bet everything else
化学名称 CAS No. 含量（%） 等级 二氧化锰 1313-13-9 36-44 Xn,R20//22 锌 7440-66-6 13-18 N,R50//53 KOH(40%) 1310-58-3 4-9 石墨, 天然的/人造的 7782-42-5 1-4 Xn,R22,R35 钢 7439-89-6 10-18 铜 12597-71-6 2-4 氧化锌 1314-13-2 < 1 Ni -镀层 7440-02-0 < 0.5 水, 纸, 塑料, 其它 -- 全下其它 | 化学名称 | CAS No. | 含量（%） | 等级 | | :---: | :---: | :---: | :---: | | 二氧化锰 | $1313-13-9$ | $36-44$ | $\mathrm{Xn}, \mathrm{R} 20 / 22$ | | 锌 | $7440-66-6$ | $13-18$ | $\mathrm{~N}, \mathrm{R} 50 / 53$ | | $\mathrm{KOH}(40 \%)$ | $1310-58-3$ | $4-9$ | | | 石墨, 天然的/人造的 | $7782-42-5$ | $1-4$ | $\mathrm{Xn}, \mathrm{R} 22, \mathrm{R} 35$ | | 钢 | $7439-89-6$ | $10-18$ | | | 铜 | $12597-71-6$ | $2-4$ | | | 氧化锌 | $1314-13-2$ | $<1$ | | | Ni -镀层 | $7440-02-0$ | $<0.5$ | | | 水, 纸, 塑料, 其它 | -- | 全下其它 | |
Impurity CAS No. Content
汞 ( Hg ) ( Hg ) (Hg)(\mathrm{Hg}) mercury ( Hg ) ( Hg ) (Hg)(\mathrm{Hg}) 7439 − 97 − 6 7439 − 97 − 6 7439-97-67439-97-6 < 1 ppm < 1 ppm < 1ppm<1 \mathrm{ppm}
铅 ( Pb ) ( Pb ) (Pb)(\mathrm{Pb}) lead ( Pb ) ( Pb ) (Pb)(\mathrm{Pb}) 7439 − 92 − 1 7439 − 92 − 1 7439-92-17439-92-1 < 2 ppm < 2 ppm < 2ppm<2 \mathrm{ppm}
镉 ( Cd ) ( Cd ) (Cd)(\mathrm{Cd}) cadmium ( Cd ) ( Cd ) (Cd)(\mathrm{Cd}) 7440 − 43 − 9 7440 − 43 − 9 7440-43-97440-43-9 < 15 ppm < 15 ppm < 15ppm<15 \mathrm{ppm}
Impurity CAS No. Content 汞 (Hg) 7439-97-6 < 1ppm 铅 (Pb) 7439-92-1 < 2ppm 镉 (Cd) 7440-43-9 < 15ppm| Impurity | CAS No. | Content | | :---: | :---: | :---: | | 汞 $(\mathrm{Hg})$ | $7439-97-6$ | $<1 \mathrm{ppm}$ | | 铅 $(\mathrm{Pb})$ | $7439-92-1$ | $<2 \mathrm{ppm}$ | | 镉 $(\mathrm{Cd})$ | $7440-43-9$ | $<15 \mathrm{ppm}$ |
注：本产品中的化学物质和金属均装在密封的罐内。，除非电池泄漏，暴露在高温下或是机械，物理，或电滥用不然内部物质不会发生暴露。危险成分由 OSHA, 29 CFR 1910.1200 定义。和或 HPA 的 WHMIS。在下丘脑。
Note: The chemicals and metals in this product are contained in sealed cans. , unless the battery leaks, is exposed to high temperatures, or is subject to mechanical, physical, or electrical abuse, no exposure of the contents will occur. Hazardous ingredients are defined by OSHA, 29 CFR 1910.1200. and or HPA's WHMIS. in the hypothalamus.

第四部分:急救措施 Part 4: First aid measures

一般建议：本产品中的化学物质和金属都是密封在电池壳中的。除非电池泄漏，暴露在高温下或机械上、物
General Advice: The chemicals and metals in this product are sealed in the battery case. Unless the battery leaks, is exposed to high temperatures or machinery or objects
理上或电滥用，否则内部物质不会暴露。 physical or electrical abuse, otherwise the contents inside will not be exposed.
损坏的电池会释放出高浓度具有腐蚀性的氢氧化钾。可预见氢氧化钾的潜在泄漏量为 2 到 20 毫升，具体取决于电池的大小。
Damaged batteries can release high concentrations of corrosive potassium hydroxide. Potential leakage volumes of potassium hydroxide can be expected to be between 2 and 20 ml, depending on the size of the battery.
眼睛接触：如果电池漏水，材料接触眼睛，用大量流动的水彻底疥洗 30 分钟。立即寻求医疗建议。
Eye Contact: If battery leaks and material comes into contact with eyes, wash thoroughly with plenty of running water for 30 minutes. Seek medical advice immediately.
皮肤接触：如果电池洲漏，材料接触皮肤，脱掉任何污染的衣服，用大量自来水冲洗暴露的皮肤至少 15 分钟。如果刺激、伤害或疼痛持续，寻求医疗建议。
Skin Contact: If battery leaks and material contacts skin, remove any contaminated clothing and flush exposed skin with plenty of tap water for at least 15 minutes. If irritation, injury or pain persists, seek medical advice.
吸 入：如果电池泄漏，内容物可能刺激呼吸道。去呼吸新鲜空气。如果刺激持续，寻求医疗建议。
Inhalation: If a battery leaks, the contents may irritate the respiratory tract. Go get some fresh air. If irritation persists, seek medical advice.
吞 食：如果电池内容物被吞食，不要引起呕吐。如果患者处于警觉状态，让他们用清水冲洗口腔和周围皮肤至少 15 分钟。立即就医。
Ingestion: If battery contents are swallowed, do not cause vomiting. If the patient is alert, have them rinse their mouth and surrounding skin with water for at least 15 minutes. Get medical attention immediately.
注：此 SDS 不包括或解决可吞食的小纽扣电池。 Note: This SDS does not include or address small coin cells that can be swallowed.

第五部分：消防措施 Part 5: Firefighting Measures

火灾和爆炸危险：当电池暴露在火灾情况下，可能会爆炸并释放出有害的分解产物。
Fire and Explosion Hazards: When exposed to fire conditions, batteries may explode and release harmful decomposition products.
灭火介质：使用任何适合周围火源的灭火介质。 Extinguishing Media: Use any extinguishing media suitable for the surrounding fire source.
特殊灭火程序：消防队员应穿戴正压自给式呼吸器和全套防护服。从远处或受保护的区域灭火。冷却暴露的电池，防止破裂。处理暴露在火下的电池容器时要小心（电池容器在火热下可能会爆炸或爆炸）。
Special fire-fighting procedures: Firefighters should wear positive-pressure self-contained breathing apparatus and full protective clothing. Fight fire from a distance or from a protected area. Cool exposed batteries to prevent rupture. Use caution when handling battery containers exposed to fire (battery containers may explode or explode when exposed to heat).
告险燃烧产品：热降解可能产生有害的锌和锰烟雾；氢气，氢氧化钾的腐蚀性蒸汽和其他有毒的副产品。
HAZARDOUS COMBUSTION PRODUCTS: Thermal degradation may produce harmful zinc and manganese fumes; hydrogen gas, corrosive vapors of potassium hydroxide and other toxic by-products.

第六部分：意外释放措施 Part Six: Accidental Release Measures

如果有重大泄漏，通知安全人员。电池泄漏或破裂可能会释放出腐蚀性的氢氧化钾。清洁人员应穿戴适当的防护服，以避免眼睛和皮肤接触和吸入蒸汽或烟雾。加强通风。小心收集电池，并放置在适当的容器中进行处理。
If there is a major leak, notify safety personnel. A leaking or ruptured battery may release corrosive potassium hydroxide. Cleaning personnel should wear appropriate protective clothing to avoid eye and skin contact and inhalation of vapors or fumes. Improve ventilation. Collect batteries carefully and place in appropriate container for disposal.

第七部分:搬运和储存 Part 7: Handling and Storage

避免机械的或电的滥用。不要短路或不正确安装。如果对电池拆卸、粉碎、充电或电池暴露在高温下，可能发生爆炸、热解或排气。按照设备说明书安装电池。不要在同一设备中同时使用不同化学体系的电池，如碱性电池和锌碳电池。同时更换设备中的所有电池。不要把电池松散地放在口袋或袋子里。请勿拆卸电池测试器或电池标签。储存：将电池置于干燥处，常温保存。不要冷藏——这不会使它们保存更久。
Avoid mechanical or electrical abuse. Do not short circuit or install incorrectly. If the battery is disassembled, crushed, charged, or exposed to high temperatures, explosion, pyrolysis, or outgassing may occur. Install the battery according to the device instructions. Do not use batteries of different chemical systems, such as alkaline batteries and zinc-carbon batteries, in the same device at the same time. Replace all batteries in the device at the same time. Do not carry batteries loose in pockets or bags. Do not remove the battery tester or battery label. Storage: Store the battery in a dry place at room temperature. Do not refrigerate - this will not make them last longer.

第八部分：暴露控制/预辐射保护 Part 8: Exposure controls/pre-radiation protection

下列职业接触暴露限值供参考之用。在消费者正常使用期间，电池内部的物质不会暴露出来。
The following occupational exposure exposure limits are for reference only. During normal consumer use, the contents inside the battery are not exposed.
有关暴露极限的其他信息，请参阅国家的具体规定。 For additional information on exposure limits, see country-specific regulations.
化学名称 chemical name 暴露限值 Exposure limits
锌 锌金属没有设限值 There is no limit for zinc metal
化学名称 暴露限值 锌 锌金属没有设限值| 化学名称 | 暴露限值 | | :--- | :--- | | 锌 | 锌金属没有设限值 |